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Preparation and characterization of polyimide/silica/silver composite films

JIANG Lizhong, WU Dezhen, LUO Ning, WU Zhanpeng, MOU Nanxiang

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 291-295 doi: 10.1007/s11705-008-0059-3

摘要： Polyimide/silica/silver hybrid films were prepared by the sol-gel method combined with single-stage self-metallization technique. The structure of polyimide films in the thermal curing process and the influence of silica content on the migration and aggregation of silver particles to the surface of hybrid films were investigated. The hybrid films were characterized by transmission electron microscopy, dynamic mechanical thermal analysis, Fourier transform infrared spectroscopy, ultraviolet visible spectroscopy and mechanical measurements. The results indicated that there was no degradation of the polyimide matrix after the formation of silica and silver particles. Silica acted as the nucleus for the silver particles. With increasing silica content, more and more silver particles were kept in the hybrid films instead of being migrated onto the surface of the hybrid films and the reflections of hybrid films decreased gradually.

关键词： single-stage self-metallization     spectroscopy     transmission     Polyimide/silica/silver     ultraviolet visible    

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First law-based thermodynamic analysis on Kalina cycle

ZHANG Ying, HE Maogang, JIA Zhen, LIU Xun

《能源前沿（英文）》 2008年 第2卷 第2期   页码 145-151 doi: 10.1007/s11708-008-0021-6

摘要： Based on the first law of thermodynamics, and adopting the Peng-Robinson equation (P-R equation) as the basic equation for the properties of ammonia-water mixtures, a thermodynamic analysis on a single-stage distillation Kalina cycle is presented. A program to calculate the thermodynamic properties of ammonia-water mixtures, and that for calculating the performance of Kalina cycles, were developed, with which the heat-work conversion particulars of Kalina cycles were theoretically calculated. The influences on the cycle performance of key parameters, such as the pressure and temperature at the inlet of the turbine, the back pressure of the turbine, the concentration of the working solution, the concentration of the basic solution and the cycle multiplication ratio, were analyzed.

关键词： ammonia-water     P-R     single-stage distillation     Peng-Robinson     pressure    

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Ionic strength directed self-assembled polyelectrolyte single-bilayer membrane for low-pressure nanofiltration

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 699-708 doi: 10.1007/s11705-021-2093-3

摘要： Layer-by-layer assembly is a versatile technique for fabricating nanofiltration membranes, where multiple layers of polyelectrolytes are usually required to achieve reasonable separation performance. In this work, an ionic strength directed self-assembly procedure is described for the preparation of nanofiltration membranes consisting of only a single bilayer of poly(diallyldimethylammoniumchloride) and poly(sodium-4-styrenesulfoate). The influence of background ionic strength as well as membrane substrate properties on the formation of single-bilayer membranes are systematically evaluated. Such a simplified polyelectrolyte deposition procedure results in membranes having outstanding separation performance with permeating flux of 14.2 ± 1.5 L∙m–2∙h–1∙bar–1 and Na2SO4 rejection of 97.1% ± 0.8% under a low applied pressure of 1 bar. These results surpass the ones for conventional multilayered polyelectrolyte membranes. This work encompasses an investigation of ionic strength induced coiling of the polyelectrolyte chains and emphasizes the interplay between-polyelectrolyte chain configuration and substrate pore profile. It thus introduces a new concept on the control of membrane fabrication process toward high performance nanofiltration.

关键词： layer-by-layer self-assembly     single bilayer     nanofiltration membrane     desalination    

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Two-stage scheduling on batch and single machines with limited waiting time constraint

Zhongshun SHI, Zewen HUANG, Leyuan SHI

《工程管理前沿（英文）》 2017年 第4卷 第3期   页码 368-374 doi: 10.15302/J-FEM-2017034

摘要： This study addresses the problem of two-stage scheduling on batch and single machines with limited waiting time constraint; thus, the makespan is minimized. A mixed-integer linear programming model is proposed for this problem. Three tight lower bounds and a heuristic algorithm are developed. The worst-case performance of the proposed algorithm is discussed. A hybrid differential evolution algorithm is also developed to improve the solution quantity. Numerical results show that the hybrid algorithm is capable of obtaining high-quality solutions and exhibits a competitive performance

关键词： batch machine     flow shop     makespan     limited waiting time    

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Theoretical modeling and experimental verifications of the single-compressor-driven three-stage Stirling-type

Haizheng DANG, Dingli BAO, Zhiqian GAO, Tao ZHANG, Jun TAN, Rui ZHA, Jiaqi LI, Ning LI, Yongjiang ZHAO, Bangjian ZHAO

《能源前沿（英文）》 2019年 第13卷 第3期   页码 450-463 doi: 10.1007/s11708-018-0569-8

摘要： This paper establishes a theoretical model of the single-compressor-driven (SCD) three-stage Stirling-type pulse tube cryocooler (SPTC) and conducts experimental verifications. The main differences between the SCD type and the multi-compressor-driven (MCD) cryocooler are analyzed, such as the distribution of the input acoustic power in each stage and the optimization of the operating parameters, in which both advantages and difficulties of the former are stressed. The effects of the dynamic temperatures are considered to improve the accuracy of the simulation at very low temperatures, and a specific simulation example aiming at 10 K is given in which quantitative analyses are provided. A SCD three-stage SPTC is developed based on the theoretical analyses and with a total input acoustic power of 371.58 W, which reaches a no-load temperature of 8.82 K and can simultaneously achieve the cooling capacities of 2.4 W at 70 K, 0.17 W at 25 K, and 0.05 W at 10 K. The performance of the SCD three-stage SPTC is slightly poorer than that of its MCD counterpart developed in the same laboratory, but the advantages of lightweight and compactness make the former more attractive to practical applications.

关键词： single-compressor-driven     three-stage     Stirling-type pulse tube cryocooler     theoretical modeling     experimental verification    

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The effect of hierarchical single-crystal ZSM-5 zeolites with different Si/Al ratios on its pore structure

Yuexin Hou, Xiaoyun Li, Minghui Sun, Chaofan Li, Syed ul Hasnain Bakhtiar, Kunhao Lei, Shen Yu, Zhao Wang, Zhiyi Hu, Lihua Chen, Bao-Lian Su

《化学科学与工程前沿（英文）》 2021年 第15卷 第2期   页码 269-278 doi: 10.1007/s11705-020-1948-3

摘要： Hierarchical single-crystal ZSM-5 zeolites with different Si/Al ratios (Hier-ZSM-5- , where = 50, 100, 150 and 200) were synthesized using an ordered mesoporous carbon-silica composite as hard template. Hier-ZSM-5- exhibits improved mass transport properties, excellent mechanical and hydrothermal stability, and higher catalytic activity than commercial bulk zeolites in the benzyl alcohol self-etherification reaction. Results show that a decrease in the Si/Al ratio in hierarchical single-crystal ZSM-5 zeolites leads to a significant increase in the acidity and the density of micropores, which increases the final catalytic conversion. The effect of porous hierarchy on the diffusion of active sites and the final catalytic activity was also studied by comparing the catalytic conversion after selectively designed poisoned acid sites. These poisoned Hier-ZSM-5- shows much higher catalytic conversion than the poisoned commercial ZSM-5 zeolite, which indicates that the numerous intracrystalline mesopores significantly reduce the diffusion path of the reactant, leading to the faster diffusion inside the zeolite to contact with the acid sites in the micropores predominating in ZSM-5 zeolites. This study can be extended to develop a series of hierarchical single-crystal zeolites with expected catalytic performance.

关键词： hierarchical zeolites     single crystalline     interconnected pores     improved diffusion performance     benzyl alcohol self-etherification reaction    

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Compressor performance of two-stage turbocharging system

HE Yituan, MA Chaochen, WEI Mingshan, ZHU Zhifu, HE Yituan

《机械工程前沿（英文）》 2008年 第3卷 第2期   页码 218-221 doi: 10.1007/s11465-008-0027-0

摘要： To study the performance of high and low stage compressors and that of the system as a whole, a two-stage turbocharging system was matched, and a special two-stage turbocharging system test bench was built. For each test curve, the speeds of the two stage turbochargers were adjusted to the fixed data, and a compressor performance experiment was performed. The results showed many differences between the corrected mass flow and the actual mass flow of the high pressure (HP) stage compressor. To find out the actual supercharging effect of the two-stage turbocharging system, it is better to adopt the actual mass flow. The two-stage turbocharging system in this paper has much higher efficiency under most operating conditions if the pressure ratio assignment is 1:1. The system can get very high supercharging pressure when the speeds of the two stage turbochargers are rather low, which ensures the system’s security and reliability.

关键词： special two-stage     HP     performance experiment     reliability     actual supercharging    

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Two-stage stochastic programming with robust constraints for the logistics network post-disruption response

《工程管理前沿（英文）》   页码 67-81 doi: 10.1007/s42524-022-0240-2

摘要： Logistics networks (LNs) are essential for the transportation and distribution of goods or services from suppliers to consumers. However, LNs with complex structures are more vulnerable to disruptions due to natural disasters and accidents. To address the LN post-disruption response strategy optimization problem, this study proposes a novel two-stage stochastic programming model with robust delivery time constraints. The proposed model jointly optimizes the new-line-opening and rerouting decisions in the face of uncertain transport demands and transportation times. To enhance the robustness of the response strategy obtained, the conditional value at risk (CVaR) criterion is utilized to reduce the operational risk, and robust constraints based on the scenario-based uncertainty sets are proposed to guarantee the delivery time requirement. An equivalent tractable mixed-integer linear programming reformulation is further derived by linearizing the CVaR objective function and dualizing the infinite number of robust constraints into finite ones. A case study based on the practical operations of the JD LN is conducted to validate the practical significance of the proposed model. A comparison with the rerouting strategy and two benchmark models demonstrates the superiority of the proposed model in terms of operational cost, delivery time, and loading rate.

关键词： logistics network design     post-disruption response strategy     two-stage stochastic programming     conditional value at risk     robust constraint    

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Efficiency measurement for mixed two-stage nonhomogeneous network processes with shared extra intermediate

Qingxian AN, Xuyang LIU, Shijie DING

《工程管理前沿（英文）》 2020年 第7卷 第2期   页码 259-274 doi: 10.1007/s42524-019-0080-x

摘要： Unreasonable allocation of shared resources reduces the system efficiency and is a considerable operational risk. Sub-processes with insufficient portion of shared resources could not help accomplish complicated tasks, and overstaffing and idle resources will occur in the sub-processes assigned with redundant shared resources. This unfair portion distribution may cause internal contradictions among sub-processes and even lead to the collapsing of the entire system. This study proposes a data-driven, mixed two-stage network data envelopment analysis model. This method aims to reasonably define the allocation portion of shared extra intermediate resources among several nonhomogeneous subsystems and measure the overall system performance. A data set of 58 international hotels is used to test the features of the proposed model.

关键词： shared resource allocation     mixed two-stage system     data envelopment analysis     efficiency    

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Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 313-319 doi: 10.1007/s11783-009-0025-4

摘要： This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact of leachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (), the reaction rate constant in the first stage (), and the reaction rate constant in the second stage () of 64.746 L, 0.202 d, and 0.338 d, respectively, were comparable to the old ones of 42.069 L, 0.231 d, and 0.231 d. The new model is better able to explain the mechanisms involved in LFG generation.

关键词： landfill gas (LFG)     generation rate model     first-order kinetics     two-stage reaction     outflow function    

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Exploring self-organization and self-adaption for smart manufacturing complex networks

《工程管理前沿（英文）》 2023年 第10卷 第2期   页码 206-222 doi: 10.1007/s42524-022-0225-1

摘要： Trends toward the globalization of the manufacturing industry and the increasing demands for small-batch, short-cycle, and highly customized products result in complexities and fluctuations in both external and internal manufacturing environments, which poses great challenges to manufacturing enterprises. Fortunately, recent advances in the Industrial Internet of Things (IIoT) and the widespread use of embedded processors and sensors in factories enable collecting real-time manufacturing status data and building cyber–physical systems for smart, flexible, and resilient manufacturing systems. In this context, this paper investigates the mechanisms and methodology of self-organization and self-adaption to tackle exceptions and disturbances in discrete manufacturing processes. Specifically, a general model of smart manufacturing complex networks is constructed using scale-free networks to interconnect heterogeneous manufacturing resources represented by network vertices at multiple levels. Moreover, the capabilities of physical manufacturing resources are encapsulated into virtual manufacturing services using cloud technology, which can be added to or removed from the networks in a plug-and-play manner. Materials, information, and financial assets are passed through interactive links across the networks. Subsequently, analytical target cascading is used to formulate the processes of self-organizing optimal configuration and self-adaptive collaborative control for multilevel key manufacturing resources while particle swarm optimization is used to solve local problems on network vertices. Consequently, an industrial case based on a Chinese engine factory demonstrates the feasibility and efficiency of the proposed model and method in handling typical exceptions. The simulation results show that the proposed mechanism and method outperform the event-triggered rescheduling method, reducing manufacturing cost, manufacturing time, waiting time, and energy consumption, with reasonable computational time. This work potentially enables managers and practitioners to implement active perception, active response, self-organization, and self-adaption solutions in discrete manufacturing enterprises.

关键词： cyber–physical systems     Industrial Internet of Things     smart manufacturing complex networks     self-organization and self-adaption     analytical target cascading     collaborative optimization    

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Exergy analysis of multi-stage crude distillation units

Xingang LI, Canwei LIN, Lei WANG, Hong LI

《化学科学与工程前沿（英文）》 2013年 第7卷 第4期   页码 437-446 doi: 10.1007/s11705-013-1349-y

摘要： This paper aims to investigate the multi-stage effect on crude distillation units (CDUs) in thermodynamics. In this regard, we proposed three-, four-, five-, and six-stage CDU processes with all variables constrained to be almost the same except for the number of stages. We also analyzed the energy and exergy to assess the energy consumed by each process. Because additional distillation units would share the processing load and thus prevent products with low boiling points from overheating, the heat demand of the CDUs decreases with increasing stages and thus reduces the heat supply. Exergy loss is considered as a key parameter to assess these processes. When the exergy losses in heat exchangers are disregarded, the three- and four-stage CDUs have lower exergy losses than the five- and six-stage CDUs. When the overall exergy losses are considered, the optimum number of stages of CDUs depends on the exergy efficiency of heat integration.

关键词： exergy     exergy loss     crude oil distillation     multi-stage     energy saving    

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Discussion on back-to-back two-stage centrifugal compressor compact design techniques

Lei HUO, Huoxing LIU

《机械工程前沿（英文）》 2013年 第8卷 第4期   页码 390-400 doi: 10.1007/s11465-013-0278-2

摘要：

Design a small flow back-to-back two-stage centrifugal compressor in the aviation turbocharger, the compressor is compact structure, small axial length, light weighted. Stationary parts have a great influence on their overall performance decline. Therefore, the stationary part of the back-to-back two-stage centrifugal compressor should pay full attention to the diffuser, bend, return vane and volute design. Volute also impact downstream return vane, making the flow in circumferential direction is not uniformed, and several blade angle of attack is drastically changed in downstream of the volute with the airflow can not be rotated to required angle. Loading of high-pressure rotor blades change due to non-uniformed of flow in circumferential direction, which makes individual blade load distribution changed, and affected blade passage load decreased to reduce the capability of work, the tip low speed range increases.

关键词： back-to-back     two-stage     centrifugal compressor     design     Internal flow    

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Simulating multiphase flow in a two-stage pusher centrifuge using computational fluid dynamics

Chong PANG, Wei TAN, Endian SHA, Yuanqing TAO, Liyan LIU

《化学科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 329-338 doi: 10.1007/s11705-012-1205-5

摘要： The design of two-stage pusher centrifuges have developed rapidly, but a good understanding of the theory behind their practice is a long-standing problem. To better understand centrifugal filter processes, the computational fluid dynamics (CFD) software program FLUENT has been used to model the three-dimensional geometry and to simulate multiphase flows based on Euler-Euler, moving mesh, dynamic mesh and porous media models. The simulation tangential velocities were a little smaller than those for rigid-body motion. In the stable flow region, the radial velocities were in good agreement with the theoretical data. Additionally, solid concentration distribution were obtained and also showed good agreement with the experimental data. These results show that this simulation method could be an effective tool to optimize the design of the two-stage pusher centrifuge.

关键词： two-stage pusher centrifuge     multiphase flow     CFD     dynamic mesh     porous media    

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Sustainability performance analysis of environment innovation systems using a two-stage network DEA model

《工程管理前沿（英文）》   页码 425-438 doi: 10.1007/s42524-022-0205-5

摘要： The term environmental innovation system refers to an innovation network composed of enterprises, universities, and research institutions involved in the development and diffusion of environmental technology, with the participation of a government. An environmental innovation system not only exerts important impact on the achievement of carbon neutrality but also affects social and economic activities. Investigations on environmental innovation system performance constantly assume a single-stage independent system while ignoring its internal structure. However, such systems are composed of environmental innovation research and development (R&D) and environmental innovation conversion subsystems. A two-stage data envelopment analysis (DEA) model is developed in this study to analyze the efficiency of Chinese regional environmental innovation system by opening the “black box” and considering shared resources. Empirical results indicated that China presents high overall environmental innovation efficiency although some regions need to improve. Regions with low efficiencies in both environmental innovation R&D (EIR) and environmental innovation conversion (EIC) subsystems should expand their investment in and strengthen the management of environmental innovation resources. Regions with low EIR efficiency should improve the absorption and transformation of environmental innovation achievements. Regions with low EIC efficiency should increase investment in the commercialization of environmental innovation achievements and encourage green economy industries, such as new energy, art, tourism, and environmental protection.

关键词： data envelopment analysis     environmental efficiency     environmental innovation system     shared resources     two-stage structure    

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标题 作者 时间 类型 操作

Preparation and characterization of polyimide/silica/silver composite films

JIANG Lizhong, WU Dezhen, LUO Ning, WU Zhanpeng, MOU Nanxiang

期刊论文

First law-based thermodynamic analysis on Kalina cycle

ZHANG Ying, HE Maogang, JIA Zhen, LIU Xun

期刊论文

Ionic strength directed self-assembled polyelectrolyte single-bilayer membrane for low-pressure nanofiltration

期刊论文

Two-stage scheduling on batch and single machines with limited waiting time constraint

Zhongshun SHI, Zewen HUANG, Leyuan SHI

期刊论文

Theoretical modeling and experimental verifications of the single-compressor-driven three-stage Stirling-type

Haizheng DANG, Dingli BAO, Zhiqian GAO, Tao ZHANG, Jun TAN, Rui ZHA, Jiaqi LI, Ning LI, Yongjiang ZHAO, Bangjian ZHAO

期刊论文

The effect of hierarchical single-crystal ZSM-5 zeolites with different Si/Al ratios on its pore structure

Yuexin Hou, Xiaoyun Li, Minghui Sun, Chaofan Li, Syed ul Hasnain Bakhtiar, Kunhao Lei, Shen Yu, Zhao Wang, Zhiyi Hu, Lihua Chen, Bao-Lian Su

期刊论文

Compressor performance of two-stage turbocharging system

HE Yituan, MA Chaochen, WEI Mingshan, ZHU Zhifu, HE Yituan

期刊论文

Two-stage stochastic programming with robust constraints for the logistics network post-disruption response

期刊论文

Efficiency measurement for mixed two-stage nonhomogeneous network processes with shared extra intermediate

Qingxian AN, Xuyang LIU, Shijie DING

期刊论文

Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

期刊论文

Exploring self-organization and self-adaption for smart manufacturing complex networks

期刊论文

Exergy analysis of multi-stage crude distillation units

Xingang LI, Canwei LIN, Lei WANG, Hong LI

期刊论文

Discussion on back-to-back two-stage centrifugal compressor compact design techniques

Lei HUO, Huoxing LIU

期刊论文

Simulating multiphase flow in a two-stage pusher centrifuge using computational fluid dynamics

Chong PANG, Wei TAN, Endian SHA, Yuanqing TAO, Liyan LIU

期刊论文

Sustainability performance analysis of environment innovation systems using a two-stage network DEA model

期刊论文